Last modified on 26 October 2014, at 08:22

Clean coal technology

This article is about technological innovations related to clean coal. For clean coal as a general concept, see clean coal.

Clean coal technology is a collection of technologies being developed to mitigate the environmental impact of coal energy generation.[1] When coal is used as a fuel source, the gaseous emissions generated by the thermal decomposition of the coal include sulphur dioxide (SO2), nitrogen oxides (NOx), carbon dioxide (CO2), mercury, and other chemical byproducts that vary depending on the type of the coal being used. These emissions have been established to have a negative impact on the environment, contributing to acid rain and climate change. As a result, clean coal technologies are being developed to remove or reduce pollutant emissions to the atmosphere. Some of the techniques that would be used to accomplish this include chemically washing minerals and impurities from the coal, gasification (see also IGCC), improved technology for treating flue gases to remove pollutants to increasingly stringent levels and at higher efficiency, carbon capture and storage technologies to capture the carbon dioxide from the flue gas and dewatering lower rank coals (brown coals) to improve the calorific value, and thus the efficiency of the conversion into electricity. Figures from the United States Environmental Protection Agency show that these technologies have made today’s coal-based generating fleet 77 percent cleaner on the basis of regulated emissions per unit of energy produced.[2]

Clean coal technology usually addresses atmospheric problems resulting from burning coal. Historically, the primary focus was on SO2 and NOx, the most important gases in causation of acid rain, and particulates which cause visible air pollution and deleterious effects on human health. More recent focus has been on carbon dioxide (due to its impact on global warming)[3] and concern over toxic species such as mercury.[4] Concerns exist regarding the economic viability of these technologies and the timeframe of delivery,[5] potentially high hidden economic costs in terms of social and environmental damage,[6] and the costs and viability of disposing of removed carbon and other toxic matter.[7][8]

TechnologyEdit

Several different technological methods are available for the purpose of carbon capture as demanded by the clean coal concept:

  • Pre-combustion capture - This involves gasification of a feedstock (such as coal) to form synthesis gas, which may be shifted to produce a H2 and CO2-rich gas mixture, from which the CO2 can be efficiently captured and separated, transported, and ultimately sequestered,[9] This technology is usually associated with Integrated Gasification Combined Cycle process configurations.[10]
  • Post-combustion capture - This refers to capture of CO2 from exhaust gases of combustion processes, typically using sorbents, solvents, or membrane separations to remove CO2 from the bulk gases.[11]
  • Oxy-fuel combustion - Fossil fuels such as coal are burned in a mixture of recirculated flue gas and oxygen, rather than in air, which largely eliminates nitrogen from the flue gas enabling efficient, low-cost CO2 capture.[12]

The Kemper County IGCC Project, a 582 MW coal gasification-based power plant, will use pre-combustion capture of CO2 to capture 65% of the CO2 the plant produces, which will be utilized/geologically sequestered in enhanced oil recovery operations.[13]

The Saskatchewan Government's Boundary Dam Integrated Carbon Capture and Sequestration Demonstration Project will use post-combustion, amine-based scrubber technology to capture 90% of the CO2 emitted by Unit 3 of the power plant; this CO2 will be pipelined to and utilized for enhanced oil recovery in the Weyburn oil fields.[14]

An oxyfuel CCS power plant operation processes the exhaust gases so as to separate the CO2 so that it may be stored or sequestered

An early example of a coal-based plant using (oxy-fuel) carbon-capture technology is Swedish company Vattenfall’s Schwarze Pumpe power station located in Spremberg, Germany, built by German firm Siemens, which went on-line in September 2008.[15][16] The facility captures CO2 and acid rain producing pollutants, separates them, and compresses the CO2 into a liquid. Plans are to inject the CO2 into depleted natural gas fields or other geological formations. Vattenfall opines that this technology is considered not to be a final solution for CO2 reduction in the atmosphere, but provides an achievable solution in the near term while more desirable alternative solutions to power generation can be made economically practical.[16]

Other examples of oxy-combustion carbon capture are in progress. In Biloela, Queensland, Australia, Callide Power Station has retrofitted a 30-MWth existing PC-fired power plant to operate in oxy-fuel mode; in Ciuden, Spain, Endesa has a newly built 30-MWth oxy-fuel plant using circulating fluidized bed combustion (CFBC) technology.[17] Babcock-ThermoEnergy's Zero Emission Boiler System (ZEBS) is oxy-combustion-based; this system features near 100% carbon-capture and according to company information virtually no air-emissions.[18]

Other carbon capture and storage technologies include those that dewater low-rank coals. Low-rank coals often contain a higher level of moisture content which contains a lower energy content per tonne. This causes a reduced burning efficiency and an increased emissions output. Reduction of moisture from the coal prior to combustion can reduce emissions by up to 50 percent.[citation needed]

The UK government's is working towards a clean energy future and supports clean coal projects across the country. In August 2010, UK-based company B9 Coal announced a clean coal project with 90% carbon capture to be put forward to DECC. This would help the UK raise its profile amongst green leaders across the world. This proposed project, gasifies coal underground and processes it to create pure streams of hydrogen and carbon dioxide. The hydrogen is then used as an emissions-free fuel to run an alkaline fuel cell whilst the carbon dioxide is captured. This UK project could provide a world-leading template for clean coal with CCS globally.

Demonstration projects in the United StatesEdit

In the late 1980s and early 1990s, the U.S. Department of Energy (DOE) began conducting a joint program with the industry and State agencies to demonstrate clean coal technologies large enough for commercial use. The program, called the Clean Coal Technology & Clean Coal Power Initiative (CCPI), has had a number of successes that have reduced emissions and waste from coal-based electricity generation.[19] The National Energy Technology Laboratory has administered three rounds of CCPI funding and the following projects were selected during each round:[20]

  • Round 1 CCPI Projects
    • Advanced Multi-Product Coal Utilization By-Product Processing Plant
    • Demonstration of Integrated Optimization Software at the Baldwin Energy Complex
    • Gilberton Coal-to-Clean Fuels and Power Co-Production Project
    • Increasing Power Plant Efficiency: Lignite Fuel Enhancement
    • TOXECON Retrofit for Mercury and Multi-Pollutant Control on Three 90-MW Coal-Fired Boilers
    • Western Greenbrier Co-Production Demonstration Project
    • Commercial Demonstration of the Airborne Process
    • Integration of Advanced Emission Controls to Produce Next-Generation Circulating Fluid Bed Coal Generating Unit
  • Round 2 CCPI Projects
    • Airborne ProcessTM Commercial Scale Demonstration Program
    • Demonstration of a Coal-Based Transport Gasifier
    • Mercury Species and Multi-Pollutant Control Project
    • Mesaba Energy Project

These programs have helped to meet regulatory challenges by incorporating pollution control technologies into a portfolio of cost-effective regulatory compliance options for conventional and developmental coal-fired power plants. This portfolio has positioned the U.S. as a top exporter of clean coal technologies such as those used for SOx, NOx and mercury, and more recently for carbon capture, consistent with a goal of deploying advanced coal-based power systems in commercial service with improved efficiency and environmental performance to meet increasingly stringent environmental regulations and market demands, leading to widespread, global deployment which will contribute to significant reductions in greenhouse gas emissions. The DOE continues its programs and initiatives through regional sequestration partnerships, a carbon sequestration leadership forum and the Carbon Sequestration Core Program, a CCS research and development program.[21]

According to a report by the assistant secretary for fossil energy at the U.S. Department of Energy, clean coal technology has paid measurable dividends. Technological innovation introduced through the CCT Program now provides consumers cost-effective, clean, coal-based energy.[22]

FutureGen is a US government project, announced by President George W. Bush in 2003 to build a near zero-emissions coal-fueled power plant to produce hydrogen and electricity while using carbon capture and storage. Funding for the original FutureGen project was withdrawn by the Department of Energy on 29 January 2008.[23] FutureGen 2.0 is the replacement project currently in development, which involves upgrading a power plant in Meredosia, Illinois with oxy-combustion technology to capture approximately 1.1 million tons of CO2 each year—more than 90 percent of the plant’s carbon emissions - to be transported and stored underground at a nearby site.[24]

Clean coal and the environmentEdit

Further information: Environmental effects of coal

According to United Nations Intergovernmental Panel on Climate Change, the burning of coal, a fossil fuel, is a major contributor to global warming. (See the UN IPCC Fourth Assessment Report). As 25.5% of the world's electrical generation in 2004 was from coal-fired generation (see World energy resources and consumption), reaching the carbon dioxide reduction targets of the Kyoto Protocol will require modifications to how coal is utilized.[25]

Coal, which is primarily used for the generation of electricity,[26] is the second largest domestic contributor to carbon dioxide emissions in the USA.[27] The public has become more concerned about global warming which has led to new legislation. The coal industry has responded by running advertising touting clean coal in an effort to counter negative perceptions and claiming more than $50 billion towards the development and deployment of "traditional" clean coal technologies over the past 30 years; and promising $500 million towards carbon capture and storage research and development.[28]

Some in the coal industry[who?] and the U.S. Department of Energy[who?] refer to carbon capture and sequestration (CCS) as the latest in "clean coal" technologies. The "clean coal" terminology is generally not endorsed by professionals in CCS, and is actively opposed by environmental organizations that favor CCS.[citation needed] CCS is a means to capture carbon dioxide from any source, compress it to a dense liquid-like state, and inject and permanently store it underground. Currently, there are more than 80 carbon capture and sequestration projects underway in the United States.[29] All components of CCS technology have been used for decades in conjunction with enhanced oil recovery and other applications; commercial-scale CCS is currently being tested in the U.S. and other countries.[by whom?] Proposed CCS sites are subjected to extensive investigation and monitoring to avoid potential hazards, which could include leakage of sequestered CO2 to the atmosphere, induced geological instability, or contamination of aquifers used for drinking water supplies.[30][31]

Supporters[who?] of clean coal use the Great Plains Synfuels plant to support the technical feasibility of carbon dioxide sequestration. Carbon dioxide from the coal gasification is shipped to Canada where it is injected into the ground to aid in oil recovery. Supporters[who?] admit that carbon sequestration is expensive.[32]

See alsoEdit

NotesEdit

  1. ^ "Coal vs. Wind". Union of Concerned Scientists. Retrieved 2008-12-30. 
  2. ^ "Air Trends". Environmental Protection Agency. 
  3. ^ "The Future of Coal". Massachusetts Institute of Technology. Retrieved 2008-12-23. 
  4. ^ "Mercury and Air Toxics Standards (MATS)". U.S. Environmental Protection Agency. Retrieved 2014-07-21. 
  5. ^ Pearce, Fred (2008-10-30). "Time to bury the ‘clean coal’ myth". London: The Guardian. Retrieved 2008-12-23. 
  6. ^ "The True Cost of Coal". Greenpeace. Retrieved 2008-12-23. 
  7. ^ "Carbon Capture and Storage". University of Edinburgh, School of Geosciences. Retrieved 2008-12-23. 
  8. ^ "Carbon Capture Plans get Reality Check". Discovery Channel. Retrieved 2008-12-23. 
  9. ^ "Pre-combustion Carbon Capture Research". Energy.gov. Office of Fossil Energy, U.S. Department of Energy. Retrieved 22 July 2014. 
  10. ^ "Picking a Winner in Clean-Coal Technology". 
  11. ^ "Post-combustion Carbon Capture Research". Energy.gov. Office of Fossil Energy, U.S. Department of Energy. 
  12. ^ "R&D Facts - Oxy-Fuel Combustion". National Energy Technology Laboratory, U.S. Department of Energy. Retrieved 22 July 2014. 
  13. ^ "IGCC Project Examples - Kemper County IGCC Project". Gasifipedia. National Energy Technology Laboratory, U.S. Department of Energy. Retrieved 22 July 2014. 
  14. ^ "Boundary Dam Integrated Carbon Capture and Sequestration Demonstration Project". Global CCS Institute. Retrieved 22 July 2014. 
  15. ^ "Vattenfall's Project on CSS". Vattenfall. 
  16. ^ a b http://discovermagazine.com/2009/feb/25-can-clean-coal-actually-work/?searchterm=clean%20coal "Can Clean Coal Actually Work?" article in Feb. 2009 issue, page 18, Retrieved 2009-05-11
  17. ^ "Overview of Oxy-fuel Combustion Technology for CO2 Capture". Cornerstone Magazine. World Coal Association. Retrieved 22 July 2014. 
  18. ^ Energy Technologies: Zero Emissions Boiler System - Combustion of Carbonaceous Fuels with Recovery of all By-Products and no CO2 or other Air Emissions
  19. ^ "Clean Coal Technology & The Clean Coal Power Initiative". U.S. Department of Energy. 
  20. ^ "Major Demonstrations: Clean Coal Power Initiative (CCPI)". NETL. Retrieved 1 May 2012. 
  21. ^ "Carbon Sequestration". U.S. Department of Energy. 
  22. ^ "Clean Coal Technology: The Investment Pays Off". U.S. Department of Energy. 
  23. ^ Department of Energy Office of Fossil Energy FutureGen page.
  24. ^ "FutureGen 2.0 Project". FutureGen Alliance. Retrieved 21 July 2014. 
  25. ^ "CRS Issue Brief for Congress - IB89005: Global Climate Change". National Council for Science and the Environment. August 13, 2001. Retrieved 2008-09-13. 
  26. ^ "U.S. Coal Supply and Demand". Energy Information Administration. Retrieved 2009-01-18. 
  27. ^ "Estimates of Monthly CO2 Emissions and Associated 13C/12 Values from Fossil-Fuel Consumption in the U.S.A.". Retrieved 2009-01-01. 
  28. ^ "ACCCE Details More than 80 CO2 Capture and Storage Projects". America's Power. Retrieved 2009-01-12. 
  29. ^ "ACCCE Details More than 80 CO2 Capture and Storage Projects". America's Power. Retrieved 2008-12-01. 
  30. ^ "AWWA warns Congress about CO2 injection concerns". American Water Works Association. July 29, 2008. Retrieved 2008-08-27. 
  31. ^ "‘Clean coal’ push concerns environmental activists". Ohio Valley Environmental Coalition. October 16, 2005. Retrieved 2008-08-09. 
  32. ^ "Carbonomics: How to Fix the Climate and Charge it to OPEC". SSRN. Retrieved 2009-01-01. 

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